Hi Leethal and I think you also misunderstand how DC/DC devices work.
You can read all the info ( advertising hype ) about these devices but this “info” does not completely explain how these devices work.
Most people see the specs for these devices, where is states they will charge at say 14.4v, and think this is the voltage they always charge at.
This is only partially correct.
They will only charge at 14.4v once the battery gets to around the 80% SoC mark, and then these devices operate at 14.4v.
With batteries at lower states of charge, these devices operate at LOWER voltages than your alternator. And they operate at lower voltages because they are current limited, something your alternator is not.
Using a similar example to yours, I was experimenting with some new isolators and discharged an Optima D34 Yellowtop 55Ah deep cycle battery down to 11.58v, or 20% SoC, which is a safe level of discharge for any new deep cycle battery.
I had a 6m length of 10mm2 twin ( 12 return length ) and when I started the motor, the voltage at the cranking battery ( which was also at 11.58v ) quickly rose to around 14.16v but the voltage at the Optima was just 13.32.
BUT, the optima was still drawing 61 amps at that voltage.
If I had installed a 20 amp DC/DC device right beside the Optima, the voltage at the Optimas terminals would have been around 12.5v, at best.
By the way, the Optima reached better than 90% SoC in under 90 minutes of driving.
It would have taken a 20 amp DC/DC device about 2.5 hours to reach the same level and this is with a small 55Ah battery.
If it had been a 75 amp Optima, the alternator would still have charged it to around 90% SoC in a little over 90 minutes but the 20 amp DC/DC device would now need around 3.5 hours to do the same.
The devices work, but no where near as well as the advertising hype would have you believe.